For
most structural applications, materials are selected by their ability to resist
fracture, rather than their strength. A canonical example of the selection
criteria of fracture toughness are bulk metallic glasses (BMGs). Fracture
toughness, its wide variation, and its mechanistic origin is, however, not well
understood in BMGs, which encompass alloys spanning from close to ideal brittle
to remarkably tough behavior. Hence, a deeper understanding of fracture
toughness is needed, which could eventually be used to develop novel BMGs with
higher resistance to fracture to unleash their broad potential applications.
Several challenges have
prevented a deeper understanding of fracture toughness and accurate
measurements in the past. Requirements of fast cooling to vitrify the liquid
BMG former can generate external contributions such as internal stresses,
cavitation, voids, and other casting defects. Such contributions may overshadow
the intrinsic fracture behavior of a BMG. In addition, sample geometries and concepts,
which have been widely used in fracture toughness studies of BMGs in the past,
have been originally developed for strain hardening crystalline metals, in
sharp contrast to the strain softening behavior of BMGs.
We have developed an
alternative method to measure fracture toughness in BMGs, based on
thermoplastic forming of BMGs. This fabrication method reduces most
of the previously identified extrinsic contributions. As a consequence, we have
increased the repeatability and relative accuracy in fracture toughness
measurements of BMGs from a scatter of ~500 % prior to our work, down to ~3%. This
highly accurate, controlled, and repeatable method suggest itself to tackle
major open questions of fracture toughness of BMGs. These include the origin of the large range of fracture
toughness in metallic glasses, what determines the length scale for a flaw
tolerance behavior in metallic glasses, and how does fracture toughness depends on chemical composition of the BMG.
Our study will build on our research during the previous
funding periods. We will measure fracture toughness for a broad range of BMG forming alloys. These data, together with results from the previous funding period, where we determined the effect of the structural state of the BMG on fracture toughness, will be used to develop a mechanistic understanding of fracture toughness. Specifically, we hypothesis that fracture toughness in BMGs is ultimately limited by the normal, cavitation strength and not by the shear strength. Furthermore, we hypothesize and will increase in the mechanistic description, that the low barrier events, likely shear transformation events, are involved in the fracture toughness of BMGs. Our theory will be describing a complete picture from microscopic events to the fracture toughness of BMGs.